
Self-Healing Polymers and Polymer Composites
by Zhang, Ming Qiu; Rong, Min ZhiBuy New
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Summary
Author Biography
Table of Contents
Preface | p. ix |
Basics of Self-Healing: State of the Art | p. 1 |
Background | p. 1 |
Adhesive Bonding for Healing Thermosetting Materials | p. 2 |
Fusion Bonding for Healing Thermoplastic Materials | p. 5 |
Bioinspired Self-Healing | p. 7 |
Intrinsic Self-Healing | p. 11 |
Self-Healing Based on Physical Interactions | p. 11 |
Self-Healing Based on Chemical Interactions | p. 18 |
Self-Healing Based on Supramolecular Interactions | p. 26 |
Extrinsic Self-Healing | p. 30 |
Self-Healing in Terms of Healant Loaded Pipelines | p. 30 |
Self-Healing in Terms of Healant Loaded Microcapsules | p. 36 |
Insights for Future Work | p. 50 |
References | p. 62 |
Theoretical Consideration and Modeling | p. 83 |
Molecular Mechanisms | p. 85 |
Self-Healing Below Glass Transition Temperature | p. 85 |
Self-Healing Above Glass Transition Temperature | p. 87 |
Healing Modeling | p. 92 |
Percolation Modeling | p. 92 |
Continuum and Molecular-Level Modeling of Fatigue Crack Retardation | p. 95 |
Continuum Damage and Healing Mechanics | p. 97 |
Discrete Element Modeling and Numerical Study | p. 98 |
Design of Self-Healing Composites | p. 100 |
Entropy Driven Self-Assembly of Nanoparticles | p. 100 |
Optimization of Microvascular Networks | p. 103 |
Concluding Remarks, 105 References | p. 106 |
Extrinsic Self-Healing via Addition Polymerization | p. 111 |
Design and Selection of Healing System | p. 112 |
Microencapsulation of Mercaptan and Epoxy by in situ Polymerization | p. 115 |
Microencapsulation of Mercaptan | p. 115 |
Microencapsulation of Epoxy | p. 122 |
Characterization of Self-Healing Functionality | p. 126 |
Self-Healing Epoxy Materials with Embedded Dual Encapsulated Healant: Healing of Crack Due to Monotonic Fracture | p. 126 |
Factors Related to Performance Improvement | p. 132 |
Self-Healing Epoxy Materials with Embedded Dual Encapsulated Healant: Healing of Fatigue Crack | p. 142 |
Self-Healing Epoxy/Glass Fabric Composites with Embedded Dual Encapsulated Healant: Healing of Impact Damage | p. 154 |
Concluding Remarks | p. 161 |
References | p. 162 |
Extrinsic Self-Healing via Cationic Polymerization | p. 167 |
Microencapsulation of Epoxy by UV Irradiation-Induced Interfacial Copolymerization | p. 170 |
Encapsulation of Boron-Containing Curing Agent | p. 186 |
Loading Boron-Containing Curing Agent onto Porous Media | p. 186 |
Microencapsulation of Boron-Containing Curing Agent via Hollow Capsules Approach | p. 189 |
Characterization of Self-Healing Functionality | p. 202 |
Self-Healing Epoxy Materials with Embedded Epoxy-Loaded Microcapsules and (C2H5)2O.BF3-Loaded Sisal | p. 202 |
Self-Healing Epoxy Materials with Embedded Dual Encapsulated Healant | p. 211 |
Concluding Remarks | p. 220 |
References | p. 221 |
Extrinsic Self-Healing via Anionic Polymerization | p. 227 |
Preparation of Epoxy-Loaded Microcapsules and Latent Hardener | p. 230 |
Microencapsulation of Epoxy by in situ Condensation | p. 230 |
Preparation of Imidazole Latent Hardener | p. 234 |
Self-Healing Epoxy Materials with Embedded Epoxy-Loaded Microcapsules and Latent Hardener | p. 236 |
Self-Healing Epoxy/Woven Glass Fabric Composites with Embedded Epoxy-Loaded Microcapsules and Latent Hardener: Healing of Interlaminar Failure | p. 243 |
Durability of Healing Ability | p. 254 |
Self-Healing Epoxy/Woven Glass Fabric Composites with Embedded Epoxy-Loaded Microcapsules and Latent Hardener: Healing of Impact Damage | p. 262 |
Concluding Remarks | p. 275 |
References | p. 276 |
Extrinsic Self-Healing via Miscellaneous Reactions | p. 281 |
Extrinsic Self-Healing via Nucleophilic Addition and Ring-Opening Reactions | p. 283 |
Microencapsulation of GMA by in situ Polymerization | p. 283 |
Self-Healing Epoxy Materials with Embedded Single-Component Healant | p. 289 |
Extrinsic Self-Healing via Living Polymerization | p. 301 |
Preparation of Living PMMA and Its Composites with GMA-Loaded Microcapsules | p. 302 |
Characterization of Self-Healing Functionality | p. 305 |
Extrinsic Self-Healing via Free Radical Polymerization | p. 315 |
Microencapsulation of Styrene and BPO | p. 315 |
Self-Healing Performance of Epoxy Filled with Dual Capsules | p. 321 |
Concluding Remarks | p. 324 |
References | p. 325 |
Intrinsic Self-Healing via Diels-Alder Reaction | p. 329 |
Molecular Design and Synthesis | p. 331 |
Synthesis and Characterization of DGFA | p. 334 |
Reversibility of DA Bonds and Crack Remendability of DGFA Based Polymer | p. 339 |
Synthesis and Characterization of FGE | p. 351 |
Reversibility of DA Bonds and Crack Remendability of FGE-Based Polymer | p. 354 |
Blends of DGFA and FGE | p. 363 |
Reversibility of DA Bonds | p. 364 |
Crack Remendability of Cured DGFA/FGE Blends | p. 369 |
Concluding Remarks, 374 References | p. 375 |
Applications | p. 379 |
Coatings and Films | p. 380 |
Elastomers | p. 386 |
Smart Composites | p. 388 |
Tires | p. 393 |
Concluding Remarks | p. 395 |
References | p. 397 |
Appendix: Nomenclature | p. 403 |
Index | p. 409 |
Table of Contents provided by Ingram. All Rights Reserved. |
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