Photoinitiated Polymerization

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Format: Hardcover
Pub. Date: 2003-03-27
Publisher(s): American Chemical Society
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Summary

Photoinitiated Polymerization is divided into five sections. Free radical photopolymerizations command most of the interest and activity within the field and thus is discussed first. The second section discusses kinetic studies of the mechanism of free radical polymerizations. The third section covers cationic photopolymerizations, which along with free radical polymerizations, are being used in many industrial applications. The fourth section is devoted to recent developments in novel photopolymeriztion chemistry. This section describes new photobase generators, developments in monomers, oligomers and templated polymerizations of liquid crystal polymers. Finally, the fifth section portrays new and emerging applications for photopolymerizations.

Table of Contents

Preface xiii
Free Radical Photopolymerization Chemistry
N-Vinylamides and Reduction of Oxygen Inhibition in Photopolymerization of Simple Acrylate Formulations
2(13)
Chris W. Miller
C. E. Hoyle
S. Jonsson
C. Nason
T. Y. Lee
W. F. Kuang
K. Viswanathan
Spectroscopic Investigation of Three-Component Initiator Systems
15(12)
Kathryn Sirovatka Padon
Dongkwan Kim
Mohamed El-Maazawi
Alec B. Scranton
A Mechanistic Description of the Sensitized N-Substituted Maleimide Initiated Photopolymerization of an Acrylate Monomer
27(14)
Chau K. Nguyen
T. Brian Cavitt
Charles E. Hoyle
Viswanathan Kalyanaraman
Sonny Jonsson
Photoinitiation of Acrylates via Sensitized Phthalimide Derivatives
41(11)
T. Brian Cavitt
Brian Phillips
Charles E. Hoyle
Chau K. Nguyen
Viswanathan Kalyanaraman
Sonny Jonsson
Photoinitiated Polymerization of Selected Thiol-ene Systems
52(13)
Charles E. Hoyle
M. Cole
M. Bachemin
W. Kuang
Viswanathan Kalyanaraman
Sonny Jonsson
Allyl Ethers in the Thiol-ene Reaction
65(11)
Ingemar Carlsson
Adrian Harden
Stefan Lundmark
Ana Manea
Nicola Rehnberg
Lennart Svensson
Mechanistic Aspects of Maleimide-Donor Photocopolymerizations
76(16)
S. Jonsson
D. Yang
K. Viswanathan
E. Shier
K. Lindgren
K. D. Belfield
C. E. Hoyle
Kinetic Studies of Free Radical Photopolymerizations
Photoinitiated Cross-Linking Polymerization of Monomer Blends
92(13)
Christian Decker
Synthesis and Photochemistry of Monodisperse Oligomeric--Polymeric Photoinitiators
105(8)
Zhiqiang Liu
Matthias Weber
Nicholas J. Turro
Ben O'Shaughnessy
Kinetics of Photopolymerization of Acrylate Coatings
113(14)
Igor V. Khudyakov
Michael B. Purvis
Nicholas J. Turro
Effect of Preorganization Due to Hydrogen Bonding on the Rate of Photoinitiated Acrylate Polymerization
127(13)
Johan F. G. A. Jansen
Aylvin A. Dias
Marko Dorschu
Betty Coussens
Photoinitiator Triplet States and Photoinitiating Radical--Monomer Interactions: Investigation through Time-Resolved Photothermal Techniques
140(12)
Xavier Allonas
Jacques Lalevee
Jean-Pierre Fouassier
Oxygen Inhibition Effect on Surface Properties of UV-Curable Acrylate Coatings
152(13)
H. Cao
E. Currie
M. Tilley
Y. C. Jean
Oxygen and Radical Photopolymerization in Films
165(13)
Vadim V. Krongauz
Chander P. Chawla
Juliette Dupre
Cationic Photopolymerization
Synergistic Free Radical Effects in Photoinitiated Cationic Polymerization
178(9)
James V. Crivello
Initiation of Cationic Polymerization by Addition--Fragmentation Reactions: Bifunctional Addition--Fragmentation Agents as Photoinitiators for Cationic Polymerization
187(15)
Yusuf Yagci
Aysen Onen
Diazonium Salts as Cationic Photoinitiators: Radical and Cationic Aspects
202(11)
U. Muller
A. Utterodt
W. Morke
B. Deubzer
Ch. Herzig
2,3-Dihydrofuran: A Special Vinyl Ether for Cationic Photopolymerization
213(6)
Oskar Nuyken
Harald Braun
Photosensitization of Onium Salt Initiated Cationic Photopolymerizations by Carbazole Monomers, Polymers, and Oligomers
219(12)
Yujing Hua
James V. Crivello
Phenothiazine Photosensitizers for Onium Salt Photoinitiated Cationic Polymerization
231(11)
Zaza Gomurashvili
James V. Crivello
Visible and Long-Wavelength Cationic Photopolymerization
242(11)
Marco Sangermano
James V. Crivello
Synthesis and Photoinitiated Cationic Polymerization of Organic--Inorganic Hybrid Resins
253(13)
Ki Yong Song
Ramakrishna Ghoshal
James V. Crivello
The Photoinitiated Cationic Polymerization of 3,4-Epoxy-1-butene
266(11)
Marco Sangermano
Stephen N. Falling
James V. Crivello
Synthesis and Photoinitiated Cationic Polymerization of Fluoroalkyl Propenyl Ethers
277(8)
Sang-Yeon Shim
Dong Hack Suh
Cationic Photopolymerization of 2-Phenyloxetanes
285(11)
Hisao Kato
Hiroshi Sasaki
Photocurable Pressure-Sensitive Adhesives Using Alkyl Oxetane
296(10)
Hiroshi Sasaki
Photocationic Curable Silsesquioxanes Having Oxetanyl Group
306(11)
Hiroshi Suzuki
Seitarou Tajima
Hiroshi Sasaki
Thermomechanical Studies of Photoinitiated Cationic Polymerization of a Cycloaliphatic Epoxy Resin
317(15)
R. T. Olsson
H. E. Bair
V. Kuck
A. Hale
New Photopolymerization Chemistry
Harvesting the Fields of Inorganic and Organometallic Photochemistry for New Photoinitiators
332(19)
Charles Kutal
Yoshikazu Yamaguchi
Wei Ding
Cynthia T. Sanderson
Xinyong Li
Gary Gamble
I. Jonathan Amster
Quaternary Ammonium N,N-Dimethyldithiocarbamates as Photobase Generators
351(12)
Masahiro Tsunooka
Hideki Tachi
Takayuki Yamamoto
Masamitsu Shirai
Synthesis and Photochemical Reaction of High-Performance UV-Curing Oligomers
363(15)
T. Nishikubo
A. Kameyama
H. Kudo
Photopolymerization Kinetics of Nanostructured Polymers Templated by Lyotropic Liquid Crystals
378(11)
C. Allan Guymon
Christopher L. Lester
Photopolymerization of Silica-Filled Composites: Encapsulants for Microelectronic Devices
389(11)
Kiran K. Baikerikar
Vishal Sipani
Chris N. Coretsopoulos
Alec B. Scranton
Photocurable, Hydrophobic Oligomers Based on Liquid Polybutadienes
400(12)
Bo Yang
Bill Schaeffer
UV-Curable Acrylated Oligomers: Effect of Structural Variation on Liquid and Cured Film Properties
412(14)
A. J. Tortorello
Real-Time Fluorescence for Determining the Relative Sensitivities of Reactive and Non-Reactive Fluorescent Probes
426(11)
Wolter F. Jager
Otto van den Berg
Continuous Photopolymerization in a Novel Thin Film Spinning Disc Reactor
437(14)
Kamelia V. K. Boodhoo
William A. E. Dunk
Roshan J. Jachuck
Pulsed Laser Polymerization of Methyl Methacrylate Using Wilkinson's Catalyst as a Photoinitiator
451(13)
M. Sakhawat Hussain
Shafique Ahmad Awan
M. A. Khan
Haleem Hamid
New and Emerging Applications for Photoinitiating Polymerizations
Two-Photon Photoinitiated Polymerization
464(18)
Kevin D. Belfield
Katherine J. Schafer
Fluorinated Distyrylbenzene Containing Copolymers for Photoinduced Formation of Anisotropic Materials as Photoalignment Layers for Liquid Crystals
482(17)
Veronika Strehmel
Burkhard Stiller
Bernd Strehmel
Ananda M. Sarker
Douglas C. Neckers
UV-Curing of Fluorinated Systems: Synthesis and Properties
499(12)
Roberta Bongiovanni
Giulio Malucelli
Aldo Priola
Autohesion of Polyethylene Plates by the Photoinduced Grafting of Methacrylamide
511(14)
Kazunori Yamada
Shigeki Takeda
Mitsuo Hirata
Indexes
Author Index
525(2)
Subject Index
527

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